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Chlorine |
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Methods
Because of its strong oxidizing properties, chlorine is an excellent biocide used to treat potable waters, municipal wastes, and swimming pools. When used to treat potable water, chlorine helps alleviate the adverse effects of iron, manganese, ammonia, and sulfide. The Maximum Residual Disinfectant Level for chlorine is 4 mg/L in drinking water.
The DPD Method
References: USEPA Methods for Chemical Analysis of Water and Wastes, Method 330.5 (1983). APHA Standard Methods, 20th ed., pp. 4-63, Method 4500-Cl G (1998).
In the USEPA-approved DPD methodology, free chlorine reacts with DPD to form a pink product. When ammonia or amines are present, some of the chlorine may exist as combined chlorine. Combined chlorine will not interfere with the free chlorine results, provided the readings are taken at one minute. To determine total chlorine (the sum of free and combined), use the A-2500 Activator Solution (potassium iodide) supplied in the kit. Results are expressed as ppm (mg/L) Cl2.
The DDPD Method
Reference: Developed by CHEMetrics, Inc.
The DDPD method is derived from the DPD method. Test kits that employ this chemistry are well suited for use where biocides and chromate corrosion inhibitors are used simultaneously. DDPD reacts with free chlorine to form a purple product. When ammonia or amines are present in the sample, some of the chlorine may exist as combined chlorine. To determine total chlorine (the sum of free and combined), use the A-2500 Activator Solution (potassium iodide) that is supplied in the kit. Results are expressed as ppm (mg/L) Cl2.
CHEMetrics’ DDPD method is also applicable to the direct determination of hypochlorite concentrations in various cleaning preparations and disinfectants prior to their dilution. The DDPD compound reacts with hypochlorite ions to form a purple color. Results are expressed as percent (%) NaOCl. |
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| • Click to View MSDS and Kit instructions |
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Visual Kits |
0-0.20 ppm
0.04 ppm / Method: DDPD |
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Cat# |
| Chlorine (free & total) ULR CHEMets Kit |
K-2511 |
| | ULR CHEMets Refill, 30 ampoules | R-2511 |
| | Activator Solution Pack, six 10 mL bottles, Shelf-life 2 years | A-2500 |
| | Neutralizer Solution Pack, six 20 mL bottles, Shelf-life 2 years | A-2501 |
| | Comparator, Shelf-life 2 years:
0, 0.04, 0.06, 0.08, 0.10, 0.12, 0.16, 0.20 ppm | C-2511 |
| | Kit comes in a plastic case and contains everything needed to perform 30 tests: Refill, Comparator, Activator Solution, Neutralizer Solution, 25 mL sample cup, instructions, and MSDS. | |
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0-1 & 1-5 ppm
0.05 ppm / Method: DPD |
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Cat# |
| Chlorine (free & total) CHEMets Kit |
K-2504 |
| | CHEMets Refill, 30 ampoules | R-2500 |
| | Activator Solution Pack, six 10 mL bottles, Shelf-life 2 years | A-2500 |
| | Low Range Comparator, Shelf-life 2 years:
0, 0.1, 0.2, 0.3, 0.4, 0.6, 0.8. 1.0 ppm | C-2504 |
| | High Range Comparator, Shelf-life 2 years:
1.0, 1.5, 2.0, 2.5, 3.0, 3.5, 4.0, 4.5, 5.0 ppm | C-2506 |
| | Kit comes in a plastic case and contains everything needed to perform 30 tests: Refill, Low and High Range Comparators, Activator Solution, 25 mL sample cup, instructions, and MSDS. | |
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0-1 & 1-5 ppm
0.05 ppm / Method: DDPD |
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Cat# |
| Chlorine (free & total) CHEMets Kit |
K-2505 |
| | CHEMets Refill, 30 ampoules | R-2505 |
| | Activator Solution Pack, six 10 mL bottles, 2 years | A-2500 |
| | Neutralizer Solution Pack, six 20 mL bottles, Shelf-life 2 years | A-2501 |
| | Low Range Comparator, Shelf-life 2 years:
0, 0.1, 0.2, 0.3, 0.4, 0.6, 0.8. 1.0 ppm | C-2501 |
| | High Range Comparator, Shelf-life 2 years:
1.0, 1.5, 2.0, 2.5, 3.0, 3.5, 4.0, 4.5, 5.0 ppm | C-2505 |
| | Kit comes in a plastic case and contains everything needed to perform 30 tests: Refill, Low and High Range Comparators, Activator Solution, Neutralizer Solution, 25 mL sample cup, instructions, and MSDS. | |
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0-30 & 30-150 ppm
5 ppm / Method: DDPD |
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Cat# |
| Chlorine (free & total) VACUettes Kit |
K-2505D |
| | VACUettes Refill, 30 ampoules | R-2505D |
| | Activator Solution Pack, six 10 mL bottles, Shelf-life 2 years | A-2500 |
| | Neutralizer Solution Pack, six 20 mL bottles, Shelf-life 2 years | A-2501 |
| | Low Range Comparator, Shelf-life 2 years:
0, 5, 7.5, 10, 15, 20, 25, 30 ppm | C-2501D |
| | High Range Comparator, Shelf-life 2 years:
30, 45, 60, 75, 87.5, 100, 112.5, 125, 150 ppm | C-2505D |
| | Kit comes in a plastic case and contains everything needed to perform 30 tests (except distilled water): Refill, Low and High Range Comparators, Activator Solution, Neutralizer Solution, dilutor snapper cup, micro test tube, instructions, and MSDS. | |
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0-60 & 60-300 ppm
10 ppm / Method: DDPD |
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Cat# |
| Chlorine (free & total) VACUettes Kit |
K-2505A |
| | VACUettes Refill, 30 ampoules | R-2505A |
| | Activator Solution Pack, six 10 mL bottles, Shelf-life 2 years | A-2500 |
| | Neutralizer Solution Pack, six 20 mL bottles, Shelf-life 2 years | A-2501 |
| | Low Range Comparator, Shelf-life 2 years:
0, 10, 15, 20, 30, 40, 50, 60 ppm | C-2501A |
| | High Range Comparator, Shelf-life 2 years:
60, 90, 120, 150, 175, 200, 225, 250, 300 ppm | C-2505A |
| | Kit comes in a plastic case and contains everything needed to perform 30 tests (except distilled water): Refill, Low and High Range Comparators, Activator Solution, Neutralizer Solution, dilutor snapper cup, micro test tube, instructions, and MSDS. | |
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0-120 & 120-600 ppm
20 ppm / Method: DDPD |
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Cat# |
| Chlorine (free & total) VACUettes Kit |
K-2505B |
| | VACUettes Refill, 30 ampoules | R-2505B |
| | Activator Solution Pack, six 10 mL bottles, Shelf-life 2 years | A-2500 |
| | Neutralizer Solution Pack, six 20 mL bottles, Shelf-life 2 years | A-2501 |
| | Low Range Comparator, Shelf-life 2 years:
0, 20, 30, 40, 60, 80, 100, 120 ppm | C-2501B |
| | High Range Comparator, Shelf-life 2 years:
120, 180, 240, 300, 350, 400, 450, 500, 600 ppm | C-2505B |
| | Kit comes in a plastic case and contains everything needed to perform 30 tests (except distilled water): Refill, Low and High Range Comparators, Activator Solution, Neutralizer Solution, dilutor snapper cup, micro test tube, instructions, and MSDS. | |
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0-1000 & 1000-5000 ppm
100 ppm / Method: DDPD |
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Cat# |
| Chlorine (free & total) VACUettes Kit |
K-2505C |
| | VACUettes Refill, 30 ampoules | R-2505C |
| | Activator Solution Pack, six 10 mL bottles, Shelf-life 2 years | A-2500 |
| | Neutralizer Solution Pack, six 20 mL bottles, Shelf-life 2 years | A-2501 |
| | Low Range Comparator, Shelf-life 2 years:
0, 100, 200, 300, 400, 600, 800, 1000 ppm | C-2501C |
| | High Range Comparator, Shelf-life 2 years:
1000, 1500, 2000, 2500, 3000, 3500, 4000, 4500, 5000 ppm | C-2505C |
| | Kit comes in a plastic case and contains everything needed to perform 30 tests (except distilled water): Refill, Low and High Range Comparators, Activator Solution, Neutralizer Solution, dilutor snapper cup, micro test tube, instructions, and MSDS. | |
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0.3-1.6% as NaOCl
0.3% / Method: DDPD |
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Cat# |
| Chlorine (hypochlorite) VACUettes Kit |
K-5805 |
| | VACUettes Refill, 30 ampoules | R-5805 |
| | Comparator, Shelf-life 2 years:
0.3, 0.45, 0.6, 0.75, 0.95, 1.15, 1.3, 1.45, 1.6% | C-5805 |
| | Kit comes in a plastic case and contains everything needed to perform 30 tests (except distilled water): Refill, Comparator, 25 mL sample cup, dilutor snapper cup, 1.0 mL syringe, micro test tube, instructions, and MSDS. | |
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2.5-13% as NaOCl
2.5% / Method: DDPD |
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Cat# |
| Chlorine (hypochlorite) VACUettes Kit |
K-5814 |
| | VACUettes Refill, 30 ampoules | R-5814 |
| | Comparator, Shelf-life 12 months:
2.5, 4, 5, 6.5, 8, 9, 10.5, 12.0, 13.0% | C-5814 |
| | Kit comes in a plastic case and contains everything needed to perform 30 tests (except distilled water): Refill, Comparator, 25 mL sample cup, dilutor snapper cup, 1.0 mL syringe, micro test tube, instructions, and MSDS. | |
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Instrumental Kits |
0.40-5.00 ppm
DPD |
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Cat# |
| Chlorine (free) Vacu-vials Kit |
K-2523 |
| | Kit comes in a cardboard box and contains everything needed to perform 30 tests: thirty ampoules, 25 mL sample cup, ampoule blank, instructions, calibration table, and MSDS. | |
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0.40-5.00 ppm
DPD |
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Cat# |
| Chlorine (free & total) Vacu-vials Kit |
K-2513 |
| | Kit comes in a cardboard box and contains everything needed to perform 30 tests: thirty ampoules, Activator Solution, 25 mL sample cup, ampoule blank, instructions, calibration table, and MSDS. | |
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0.40-5.00 ppm
DPD |
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Cat# |
| Chlorine (free & total) SAM Kit |
I-2001 |
| | Vacu-vials Kit, 30 ampoules, Activator Solution, 25 mL sample cup, ampoule blank, instructions, calibration table, and MSDS. | K-2513 |
| | SAM Kit comes in a plastic case and contains everything needed to perform 30 tests: Vacu-vials Kit, SAM Photometer, 2 AA batteries, and instructions. | |
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Kit Components common to Chlorine |
| Description |
Cat# |
| | Sample Cup Pack, 25 mL (6 ea) | A-0013 |
| | Micro Test Tube Pack (10 ea) | A-0015 |
| | Dilutor Snapper Cup Pack (6 ea) | A-0018 |
| | Ampoule Blank Pack (5 ea) | A-0023 |
| | Syringe Pack, 1.0 mL (6 ea) | A-0027 |
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