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  Chlorine
 
Methods

Because of its strong oxidizing properties, chlorine is an excellent biocide used to treat potable waters, municipal wastes, and swimming pools. When used to treat potable water, chlorine helps alleviate the adverse effects of iron, manganese, ammonia, and sulfide. The Maximum Residual Disinfectant Level for chlorine is 4 mg/L in drinking water.

The DPD Method

References: USEPA Methods for Chemical Analysis of Water and Wastes, Method 330.5 (1983). APHA Standard Methods, 20th ed., pp. 4-63, Method 4500-Cl G (1998).

In the USEPA-approved DPD methodology, free chlorine reacts with DPD to form a pink product. When ammonia or amines are present, some of the chlorine may exist as combined chlorine. Combined chlorine will not interfere with the free chlorine results, provided the readings are taken at one minute. To determine total chlorine (the sum of free and combined), use the A-2500 Activator Solution (potassium iodide) supplied in the kit. Results are expressed as ppm (mg/L) Cl2.

The DDPD Method

Reference: Developed by CHEMetrics, Inc.
The DDPD method is derived from the DPD method. Test kits that employ this chemistry are well suited for use where biocides and chromate corrosion inhibitors are used simultaneously. DDPD reacts with free chlorine to form a purple product. When ammonia or amines are present in the sample, some of the chlorine may exist as combined chlorine. To determine total chlorine (the sum of free and combined), use the A-2500 Activator Solution (potassium iodide) that is supplied in the kit. Results are expressed as ppm (mg/L) Cl2.

CHEMetrics’ DDPD method is also applicable to the direct determination of hypochlorite concentrations in various cleaning preparations and disinfectants prior to their dilution. The DDPD compound reacts with hypochlorite ions to form a purple color. Results are expressed as percent (%) NaOCl.
 
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  Visual Kits
0-0.20 ppm
0.04 ppm / Method: DDPD
  Cat#
Chlorine (free & total) ULR CHEMets Kit K-2511

ULR CHEMets Refill, 30 ampoulesR-2511

Activator Solution Pack, six 10 mL bottles, Shelf-life 2 yearsA-2500

Neutralizer Solution Pack, six 20 mL bottles, Shelf-life 2 yearsA-2501

Comparator, Shelf-life 2 years: 0, 0.04, 0.06, 0.08, 0.10, 0.12, 0.16, 0.20 ppmC-2511

Kit comes in a plastic case and contains everything needed to perform 30 tests: Refill, Comparator, Activator Solution, Neutralizer Solution, 25 mL sample cup, instructions, and MSDS.
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0-1 & 1-5 ppm
0.05 ppm / Method: DPD
  Cat#
Chlorine (free & total) CHEMets Kit K-2504

CHEMets Refill, 30 ampoulesR-2500

Activator Solution Pack, six 10 mL bottles, Shelf-life 2 yearsA-2500

Low Range Comparator, Shelf-life 2 years: 0, 0.1, 0.2, 0.3, 0.4, 0.6, 0.8. 1.0 ppmC-2504

High Range Comparator, Shelf-life 2 years: 1.0, 1.5, 2.0, 2.5, 3.0, 3.5, 4.0, 4.5, 5.0 ppmC-2506

Kit comes in a plastic case and contains everything needed to perform 30 tests: Refill, Low and High Range Comparators, Activator Solution, 25 mL sample cup, instructions, and MSDS.
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0-1 & 1-5 ppm
0.05 ppm / Method: DDPD
  Cat#
Chlorine (free & total) CHEMets Kit K-2505

CHEMets Refill, 30 ampoulesR-2505

Activator Solution Pack, six 10 mL bottles, 2 yearsA-2500

Neutralizer Solution Pack, six 20 mL bottles, Shelf-life 2 yearsA-2501

Low Range Comparator, Shelf-life 2 years: 0, 0.1, 0.2, 0.3, 0.4, 0.6, 0.8. 1.0 ppmC-2501

High Range Comparator, Shelf-life 2 years: 1.0, 1.5, 2.0, 2.5, 3.0, 3.5, 4.0, 4.5, 5.0 ppmC-2505

Kit comes in a plastic case and contains everything needed to perform 30 tests: Refill, Low and High Range Comparators, Activator Solution, Neutralizer Solution, 25 mL sample cup, instructions, and MSDS.
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0-30 & 30-150 ppm
5 ppm / Method: DDPD
  Cat#
Chlorine (free & total) VACUettes Kit K-2505D

VACUettes Refill, 30 ampoulesR-2505D

Activator Solution Pack, six 10 mL bottles, Shelf-life 2 yearsA-2500

Neutralizer Solution Pack, six 20 mL bottles, Shelf-life 2 yearsA-2501

Low Range Comparator, Shelf-life 2 years: 0, 5, 7.5, 10, 15, 20, 25, 30 ppmC-2501D

High Range Comparator, Shelf-life 2 years: 30, 45, 60, 75, 87.5, 100, 112.5, 125, 150 ppmC-2505D

Kit comes in a plastic case and contains everything needed to perform 30 tests (except distilled water): Refill, Low and High Range Comparators, Activator Solution, Neutralizer Solution, dilutor snapper cup, micro test tube, instructions, and MSDS.
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0-60 & 60-300 ppm
10 ppm / Method: DDPD
  Cat#
Chlorine (free & total) VACUettes Kit K-2505A

VACUettes Refill, 30 ampoulesR-2505A

Activator Solution Pack, six 10 mL bottles, Shelf-life 2 yearsA-2500

Neutralizer Solution Pack, six 20 mL bottles, Shelf-life 2 yearsA-2501

Low Range Comparator, Shelf-life 2 years: 0, 10, 15, 20, 30, 40, 50, 60 ppmC-2501A

High Range Comparator, Shelf-life 2 years: 60, 90, 120, 150, 175, 200, 225, 250, 300 ppmC-2505A

Kit comes in a plastic case and contains everything needed to perform 30 tests (except distilled water): Refill, Low and High Range Comparators, Activator Solution, Neutralizer Solution, dilutor snapper cup, micro test tube, instructions, and MSDS.
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0-120 & 120-600 ppm
20 ppm / Method: DDPD
  Cat#
Chlorine (free & total) VACUettes Kit K-2505B

VACUettes Refill, 30 ampoulesR-2505B

Activator Solution Pack, six 10 mL bottles, Shelf-life 2 yearsA-2500

Neutralizer Solution Pack, six 20 mL bottles, Shelf-life 2 yearsA-2501

Low Range Comparator, Shelf-life 2 years: 0, 20, 30, 40, 60, 80, 100, 120 ppmC-2501B

High Range Comparator, Shelf-life 2 years: 120, 180, 240, 300, 350, 400, 450, 500, 600 ppmC-2505B

Kit comes in a plastic case and contains everything needed to perform 30 tests (except distilled water): Refill, Low and High Range Comparators, Activator Solution, Neutralizer Solution, dilutor snapper cup, micro test tube, instructions, and MSDS.
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0-1000 & 1000-5000 ppm
100 ppm / Method: DDPD
  Cat#
Chlorine (free & total) VACUettes Kit K-2505C

VACUettes Refill, 30 ampoulesR-2505C

Activator Solution Pack, six 10 mL bottles, Shelf-life 2 yearsA-2500

Neutralizer Solution Pack, six 20 mL bottles, Shelf-life 2 yearsA-2501

Low Range Comparator, Shelf-life 2 years: 0, 100, 200, 300, 400, 600, 800, 1000 ppmC-2501C

High Range Comparator, Shelf-life 2 years: 1000, 1500, 2000, 2500, 3000, 3500, 4000, 4500, 5000 ppmC-2505C

Kit comes in a plastic case and contains everything needed to perform 30 tests (except distilled water): Refill, Low and High Range Comparators, Activator Solution, Neutralizer Solution, dilutor snapper cup, micro test tube, instructions, and MSDS.
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0.3-1.6% as NaOCl
0.3% / Method: DDPD
  Cat#
Chlorine (hypochlorite) VACUettes Kit K-5805

VACUettes Refill, 30 ampoulesR-5805

Comparator, Shelf-life 2 years: 0.3, 0.45, 0.6, 0.75, 0.95, 1.15, 1.3, 1.45, 1.6%C-5805

Kit comes in a plastic case and contains everything needed to perform 30 tests (except distilled water): Refill, Comparator, 25 mL sample cup, dilutor snapper cup, 1.0 mL syringe, micro test tube, instructions, and MSDS.
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2.5-13% as NaOCl
2.5% / Method: DDPD
  Cat#
Chlorine (hypochlorite) VACUettes Kit K-5814

VACUettes Refill, 30 ampoulesR-5814

Comparator, Shelf-life 12 months: 2.5, 4, 5, 6.5, 8, 9, 10.5, 12.0, 13.0%C-5814

Kit comes in a plastic case and contains everything needed to perform 30 tests (except distilled water): Refill, Comparator, 25 mL sample cup, dilutor snapper cup, 1.0 mL syringe, micro test tube, instructions, and MSDS.
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  Instrumental Kits
0.40-5.00 ppm
DPD
  Cat#
Chlorine (free) Vacu-vials Kit K-2523

Kit comes in a cardboard box and contains everything needed to perform 30 tests: thirty ampoules, 25 mL sample cup, ampoule blank, instructions, calibration table, and MSDS.
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0.40-5.00 ppm
DPD
  Cat#
Chlorine (free & total) Vacu-vials Kit K-2513

Kit comes in a cardboard box and contains everything needed to perform 30 tests: thirty ampoules, Activator Solution, 25 mL sample cup, ampoule blank, instructions, calibration table, and MSDS.
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0.40-5.00 ppm
DPD
  Cat#
Chlorine (free & total) SAM Kit I-2001

Vacu-vials Kit, 30 ampoules, Activator Solution, 25 mL sample cup, ampoule blank, instructions, calibration table, and MSDS.K-2513

SAM Kit comes in a plastic case and contains everything needed to perform 30 tests: Vacu-vials Kit, SAM Photometer, 2 AA batteries, and instructions.
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Kit Components common to Chlorine
Description Cat#

Sample Cup Pack, 25 mL (6 ea)A-0013

Micro Test Tube Pack (10 ea)A-0015

Dilutor Snapper Cup Pack (6 ea)A-0018

Ampoule Blank Pack (5 ea)A-0023

Syringe Pack, 1.0 mL (6 ea)A-0027
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